Given below are two statement: one is labelled as
Assertion (A) and the other is labelled as Reason (R):
Assertion (A): qImage681c67bcaf6696eb69dfe015undergoes SN2 reaction faster than qImage681c67bdaf6696eb69dfe017.

Reason (R): Iodine is a better leaving group because of its large size.

In the light of the above statements, choose the correct answer from the options given below: 

This question was previously asked in
NEET 2025 Official Paper (Held On: 04 May, 2025)
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  1. Both A and R are true and R is the correct explanation of A.
  2. Both A and R are true but R is not the correct explanation of A.
  3. A is true but R is false.
  4. A is false but R is true.

Answer (Detailed Solution Below)

Option 1 : Both A and R are true and R is the correct explanation of A.
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Detailed Solution

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CONCEPT:

SN2 Reaction and Leaving Group

  • SN2 (Substitution Nucleophilic Bimolecular) reaction is a single-step reaction where the nucleophile attacks the substrate and the leaving group departs simultaneously.
  • The rate of SN2 reaction depends on factors such as steric hindrance, the strength of the nucleophile, and the nature of the leaving group.
  • A good leaving group facilitates the reaction. A good leaving group is one that can stabilize the negative charge after leaving the substrate.
  • In halides, the leaving group ability increases with size due to better stabilization of the negative charge. Thus, Iodine (I-) is a better leaving group than Bromine (Br-).

EXPLANATION:

  • Assertion (A): "undergoes SN2 reaction faster than ." This statement is true because iodine is a better leaving group compared to bromine due to its larger size and ability to stabilize the negative charge more effectively.
  • Reason (R): "Iodine is a better leaving group because of its large size." This statement is true and correctly explains the assertion.

In SN2 reactions, the leaving group plays a crucial role in determining the reaction rate. Since iodine is a better leaving group than bromine, the substrate with iodine will undergo the SN2 reaction faster.

Therefore, the correct answer is Both A and R are true and R is the correct explanation of A.

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