Question
Download Solution PDFGiven below are two statement: one is labelled as
Assertion (A) and the other is labelled as Reason (R):
Assertion (A): undergoes SN2 reaction faster than
.
Reason (R): Iodine is a better leaving group because of its large size.
In the light of the above statements, choose the correct answer from the options given below:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
SN2 Reaction and Leaving Group
- SN2 (Substitution Nucleophilic Bimolecular) reaction is a single-step reaction where the nucleophile attacks the substrate and the leaving group departs simultaneously.
- The rate of SN2 reaction depends on factors such as steric hindrance, the strength of the nucleophile, and the nature of the leaving group.
- A good leaving group facilitates the reaction. A good leaving group is one that can stabilize the negative charge after leaving the substrate.
- In halides, the leaving group ability increases with size due to better stabilization of the negative charge. Thus, Iodine (I-) is a better leaving group than Bromine (Br-).
EXPLANATION:
- Assertion (A): "undergoes SN2 reaction faster than ." This statement is true because iodine is a better leaving group compared to bromine due to its larger size and ability to stabilize the negative charge more effectively.
- Reason (R): "Iodine is a better leaving group because of its large size." This statement is true and correctly explains the assertion.
In SN2 reactions, the leaving group plays a crucial role in determining the reaction rate. Since iodine is a better leaving group than bromine, the substrate with iodine will undergo the SN2 reaction faster.
Therefore, the correct answer is Both A and R are true and R is the correct explanation of A.
Last updated on Jun 16, 2025
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