Among Si3N4, α-BN, AlN and (SN)x, the compound with the highest conductivity is

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CSIR-UGC (NET) Chemical Science: Held on (18 Sept 2022)
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  1. Si3N4
  2. α-BN
  3. AlN
  4. (SN)x

Answer (Detailed Solution Below)

Option 4 : (SN)x
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Detailed Solution

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Explanation:-

  • (SN)x is the chemical formula for a polymer of sulfur nitride, and it is commonly referred to as "polymeric nitrogen" or "sulfur nitride polymer." This compound has been hypothesized to exist under high-pressure conditions, and it is believed to have intriguing electronic properties.
  • Experimental studies and theoretical calculations have suggested that (SN)x may exhibit metallic or semi-metallic behavior, indicating the possibility of high electrical conductivity.
  • However, it's important to note that (SN)x is a relatively theoretical material, and its properties and behavior are not yet fully understood due to its challenging synthesis and stability under ambient conditions.
  • In contrast, Si3N4 (silicon nitride), α-BN (hexagonal boron nitride), and AlN (aluminum nitride) are generally insulating materials and are not expected to exhibit high electrical conductivity under normal conditions.

Conclusion:-

  • Hence, among the compounds Si3N4, α-BN, AlN, and (SN)x, the compound with the highest conductivity is likely to be (SN)x.
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