According to Kelvin-Plank's statement of second law of thermodynamics

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  1. it is impossible to construct an engine working on a cyclic process, whose sole purpose is to convert heat energy into work.
  2. it is possible to construct an engine working on a cyclic process, whose sole purpose is to convert heat energy into work.
  3. it is impossible to construct a device which operates in a cyclic process and produces no effect other than transfer of heat from a cold body to a hot body.
  4. None of the above

Answer (Detailed Solution Below)

Option 1 : it is impossible to construct an engine working on a cyclic process, whose sole purpose is to convert heat energy into work.
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Detailed Solution

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Explanation:

 

Kelvin-Planck's statement:

  • It is impossible for any system to operate in a cycle and deliver a net amount of energy by work to its surroundings while receiving energy by heat from a single thermal reservoir.
  • This implies it is impossible to build a heat engine whose thermal efficiency is 100% and it is known as PMM-II.
  • It gives the relationship for conversion of heat into work.

F1 Sumit Madhu 17.08.20 D 2

QH = Qinput, W = Woutput

\(\eta\ =\ \frac{W_{output}}{Q_{input}}\) = 100%

The above efficiency is not possible according to PPM-II and Kelvin-Planck's law

Additional Information

Clausius statement:

  • It is impossible for any system to operate in such a way that the sole result would be an energy transfer by heat from a cooler body to a hotter body.
  • This implies it is impossible to construct a refrigerator that operates without an input of work.

F1 Sumit Madhu 17.08.20 D 1

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