Which of the following is not an electrophile?

This question was previously asked in
70th BPSC Exam Official Paper (Re-exam held on 4th January 2025) Test
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  1. Na+
  2. \(BF^{-}_{3}\)
  3. H+
  4. All of the above

Answer (Detailed Solution Below)

Option 1 : Na+
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Detailed Solution

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The correct answer is option 1.

Key Points

  • Electrophiles are species that seek electrons and can accept an electron pair. They are electron-deficient and usually have a positive charge or an incomplete octet.
  • Na⁺ (Sodium ion) is a cation, but it is not an electrophile because it does not have an empty orbital to accept electrons. Instead, it is a positively charged spectator ion and does not actively participate in electrophilic reactions. Hence, option 1 is correct.
  • BF₃ (Boron trifluoride) is an electrophile because boron has an incomplete octet and can accept electron pairs.
  • H⁺ (Proton) is a strong electrophile as it has no electrons and readily accepts electron pairs. 
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