Which of the following electronic configurations is correct according to Hund’s rule? 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. qImage684fe60c9077139382eb432d
  2. qImage684fe60c9077139382eb4330
  3. qImage684fe60d9077139382eb4331
  4. qImage684fe60d9077139382eb4398

Answer (Detailed Solution Below)

Option 4 : qImage684fe60d9077139382eb4398
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Detailed Solution

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CONCEPT:

Hund's Rule of Maximum Multiplicity

  • Hund's Rule states that electrons occupy all the degenerate (same energy) orbitals singly before pairing begins.
  • This minimizes electron–electron repulsion and maximizes total spin, which is more stable.
  • All singly occupied orbitals must have electrons with parallel spins (same direction).

EXPLANATION:

  • In the image, the question is about identifying which configuration follows Hund's Rule correctly.
  • qImage684fe60c9077139382eb432d
    Option 1: Electrons are paired before all orbitals are singly filled → Violates Hund's Rule.
  • qImage684fe60c9077139382eb4330
    Option 2: All orbitals are singly occupied, but with different spins → Violates Hund's Rule.
  • qImage684fe60d9077139382eb4331
    Option 3: First orbital has two electrons, second and third have one → Not the lowest energy configuration.
  • qImage684fe60d9077139382eb4398
    Option 4: All three degenerate orbitals are singly occupied with parallel spins → Correct as per Hund's Rule 

Therefore, the correct electronic configuration according to Hund's Rule is:
Option 4

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