Number of electrons present in the species H2+, He, H2 and O2+ respectively are:

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UPSC CDS-I 2025 (General Studies) Official Paper (Held On: 13 Apr, 2025)
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  1. 1, 2, 2, 15
  2. 1, 2, 1, 14
  3. 2, 2, 2, 16
  4. 0, 2, 1, 14

Answer (Detailed Solution Below)

Option 1 : 1, 2, 2, 15
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The correct answer is Option 1.

Key Points

  • The number of electrons in a species is determined by the atomic number of the element and its charge (if it is an ion).
  • For H2+, the molecule has lost one electron, leaving it with 1 electron.
  • Helium (He) is a neutral atom with an atomic number of 2, so it has 2 electrons.
  • For H2, each hydrogen atom contributes 1 electron, making a total of 2 electrons.
  • O2+ is an ion where one electron has been removed from the neutral O2 molecule (16 electrons in total), leaving it with 15 electrons.

Additional Information

  • Electron Counting in Ions:
    • In a positively charged ion, electrons are subtracted from the neutral atom’s count.
    • For a negatively charged ion, electrons are added to the neutral atom’s count.
  • Atomic Number:
    • The atomic number of an element represents the number of protons in its nucleus.
    • In a neutral atom, the number of protons equals the number of electrons.
  • Molecular Electron Count:
    • For diatomic molecules like H2 and O2, the total number of electrons is the sum of the electrons from each atom.
    • For charged molecules (e.g., H2+ or O2+), adjust the electron count based on the charge.
  • General Case:
    • H2+: 2 electrons in H2 minus 1 (due to the +1 charge) = 1 electron.
    • He: Atomic number 2 = 2 electrons (neutral atom).
    • H2: 1 electron from each H atom = 2 electrons (neutral molecule).
    • O2+: 16 electrons in O2 minus 1 (due to the +1 charge) = 15 electrons.
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