In 3‐iron ferredoxins, the number of sulfide bridges and cysteinyl ligands, respectively, are:

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CSIR-UGC (NET) Chemical Science: Held on (16 Feb 2022)
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  1. 3, 3
  2. 4, 3
  3. 3, 4
  4. 4, 4

Answer (Detailed Solution Below)

Option 2 : 4, 3
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Concept:

  • Ferredoxins are soluble and iron based proteins containin iron-sulphur clusters.
  • These function in electron transfer in photosystem during photosynthesis.
  • Three types of ferredoxin proteins have been isolated. These are [2Fe-2S], [3Fe-4S] and [4Fe-4S].
  • S in the presentation are labile sulphurs of cysteine which are removed easily on treatment with acid.

 

Explanation:

Structure of 3-iron ferredoxin is as given below :

F3 Vinanti Teaching 04.01.23 D39

Clearly, 3 cysteinyl ligands and 4 sulphur bridges are present in each unit

 

Conclusion:

Therefore, 3‐iron ferredoxins consist of 4 sulfide bridges and 3 cysteinyl ligands.

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