According to Lewis concept, the trend in the relative basic strengths of \(\rm ClO_4^-, ClO_3^-, ClO_2^-\)is: 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. \(\rm ClO_4^->ClO_3^-, ClO_2^-\)
  2. \(\rm ClO_3^->ClO_2^-, ClO_4^-\)
  3. \(\rm ClO_2^->ClO_3^-, ClO_4^-\)
  4. \(\rm ClO_4^->ClO_2^-, ClO_3^-\)

Answer (Detailed Solution Below)

Option 3 : \(\rm ClO_2^->ClO_3^-, ClO_4^-\)
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CONCEPT:

Lewis Basic Strength

  • According to the Lewis concept, a base is a species that can donate an electron pair.
  • In oxyanions of chlorine (ClO-, ClO2-, ClO3-, ClO4-), the basicity depends on the electron density available on the oxygen atoms.
  • As the oxidation number of chlorine increases, it pulls electron density towards itself due to increased electronegativity (inductive effect).
  • This reduces the availability of electron density on oxygen atoms for donation, decreasing Lewis basic strength.

EXPLANATION:

  • Oxidation states of chlorine in the given ions are:
    • ClO2-: +3
    • ClO3-: +5
    • ClO4-: +7
  • Higher oxidation state increases the electron-withdrawing power of chlorine, which reduces the electron density on the ion.
  • Hence, ClO2- has the highest basic strength, followed by ClO3-, and then ClO4-.

Therefore, the correct order of Lewis basic strength is ClO2- > ClO3- > ClO4-

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