Question
Download Solution PDFAccording to Lewis concept, the trend in the relative basic strengths of \(\rm ClO_4^-, ClO_3^-, ClO_2^-\)is:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Lewis Basic Strength
- According to the Lewis concept, a base is a species that can donate an electron pair.
- In oxyanions of chlorine (ClO-, ClO2-, ClO3-, ClO4-), the basicity depends on the electron density available on the oxygen atoms.
- As the oxidation number of chlorine increases, it pulls electron density towards itself due to increased electronegativity (inductive effect).
- This reduces the availability of electron density on oxygen atoms for donation, decreasing Lewis basic strength.
EXPLANATION:
- Oxidation states of chlorine in the given ions are:
- ClO2-: +3
- ClO3-: +5
- ClO4-: +7
- Higher oxidation state increases the electron-withdrawing power of chlorine, which reduces the electron density on the ion.
- Hence, ClO2- has the highest basic strength, followed by ClO3-, and then ClO4-.
Therefore, the correct order of Lewis basic strength is ClO2- > ClO3- > ClO4-
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